EPL is available also on-line on www.epljournal.org
Issue Europhys. Lett.
Volume 57, Number 6, March 2002
Page(s) 859 - 865
Section Condensed matter: electronic structure, electrical, magnetic, and optical properties
DOI http://dx.doi.org/10.1209/epl/i2002-00589-8

DOI: 10.1209/epl/i2002-00589-8


Europhys. Lett., 57 (6) , pp. 859-865 (2002)

Observation of a quasi-1D Mott-Hubbard insulator: The re-entrant $\chem{Na/Si(111)}$- $3 \times 1$ surface

J. R. Ahn1, N. D. Kim1, S. S. Lee1, K. D. Lee1, B. D. Yu2, D. Jeon3, K. Kong4 and J. W. Chung1

1  Physics Department and Basic Science Research Institute, Pohang University of Science and Technology - San 31 Hyoja Dong, Pohang 790-784, Korea
2  Department of Physics, University of Seoul - 90 Cheonnong-dong Tongdaemun-gu, Seoul 130-743, Korea
3  Department of Physics, Myong Ji University - Yongin Kyunggi-Do Seoul 449-728, Korea
4  IQUIPS, University of Seoul - 90 Cheonnong-dong, Tongdaemun-gu Seoul 130-743, Korea

(Received 13 August 2001; accepted 19 December 2001)

Abstract
We have investigated the origin of a semiconducting phase of the re-entrant $\chem{Na/Si(111)}$- $3 \times 1$ surface formed by adding extra adatoms on the earlier $3 \times 1$ phase at 1/3 monolayers (MLs). The additional $\chem{Na}$ adatoms are found to form quasi-one-dimensional (1D) atomic chains in our scanning tunnelling microscopy images while keeping the surface semiconducting. The unique features in our valence band and in high-resolution electron-energy-loss spectra suggest that the re-entrant $3 \times 1$ surface is a Mott-Hubbard-type insulator. We thus report a novel quasi-1D insulator-insulator transition where electron-electron correlation plays a decisive role.

PACS
71.30.+h - Metal-insulator transitions and other electronic transitions.
73.20.-r - Electron states at surfaces and interfaces.
61.18.-j - Other methods of structure determination.


© EDP Sciences 2002