A lattice model of hydrophobic interactionsD. W. Hone1, 2 and P. A. Pincus1, 3, 4
1 Physics Department, UCSB - Santa Barbara, CA 93106, USA
2 Kavli Institute for Theoretical Physics, UCSB - Santa Barbara, CA 93106, USA
3 Materials Department and Biomolecular Science and Engineering, UCSB Santa Barbara, CA 93106, USA
4 Physics Department, KAIST - Daejon, South Korea
received 28 August 2006; accepted in final form 16 October 2006
published online 10 November 2006
Hydrogen bonding is modeled in terms of virtual exchange of protons between water molecules. A simple lattice model is analyzed, using ideas and techniques from the theory of correlated electrons in metals. Reasonable parameters reproduce observed magnitudes and temperature dependence of the hydrophobic interaction between substitutional impurities and water within this lattice.
82.30.Rs - Hydrogen bonding, hydrophilic effects.
© EDP Sciences 2006