Structure resonances for charged clusters in liquids
CEA Saclay, LIONS, IRAMIS, CEA - F-91191, Gif-Sur-Yvette, France, EU
2 Institute of Solid State Physics of RAS - Chernogolovka, Moscow district, 142432, Russia
Accepted: 28 April 2010
Discussed in the paper are resonance phenomena in electrolytes related to possible relative motion of the charged core and hydrate (solvate) shell of individual clusters. The resonances are shown to contain important information on the internal structure of clusters. Special attention is paid to the process of formation of a cluster associated mass in the solvent. It is also shown that finite solvent viscosity does not suppress completely the structure resonance.
PACS: 66.10.-x – Diffusion and ionic conduction in liquids / 66.10.Ed – Ionic conduction
© EPLA, 2010