Volume 39, Number 1, July I 1997
|Page(s)||25 - 30|
|Section||Condensed matter: structure, thermal and mechanical properties|
|Published online||01 September 2002|
Growth of living polymers in a good solvent
Kolloid- und Grenzflächenforschung, Kantstrasse 55, D-14513 Teltow-Seehof, Germany
Accepted: 26 May 1997
Conformation space renormalisation group theory is applied to study the size distribution of living or self-assembling polymers in good solvents. In dilute solution the aggregate size distribution is found to be of the Schulz-Zimm type. It crosses over to an (almost) exponential distribution in the semi-dilute regime. The growth exponent, describing the power law dependence of the mean aggregate size on the concentration, changes from in dilute to in semi-dilute solution, to first order in with the dimensionality of space.
PACS: 61.25.Hq – Macromolecular and polymer solutions; polymer melts; swelling / 82.35.+t – Polymer reactions and polymerization / 82.70.-y – Disperse systems
© EDP Sciences, 1997
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