Issue |
Europhys. Lett.
Volume 41, Number 3, february I 1998
|
|
---|---|---|
Page(s) | 303 - 308 | |
Section | Condensed matter: structure, thermal and mechanical properties | |
DOI | https://doi.org/10.1209/epl/i1998-00147-6 | |
Published online | 01 September 2002 |
Detachment of a single polyelectrolyte chain adsorbed on a charged surface
Institut Charles Sadron (CNRS UPR 22), 6 rue Boussingault,
67083 Strasbourg Cedex, France
Received:
4
July
1997
Accepted:
4
December
1997
We study both experimentally, with an atomic force microscope (AFM), and theoretically, using scaling arguments, the stretching of a single polyelectrolyte chain adsorbed at a planar charged surface. The main result is that the force needed to pull a monomer of the chain at a distance z from the surface reaches a plateau at distances larger than the Debye screening length of the solution.
PACS: 68.45.-v – Solid-fluid interfaces / 82.65.Dp – Thermodynamics of surfaces and interfaces / 82.70.Dd – Colloids
© EDP Sciences, 1998
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