Issue |
Europhys. Lett.
Volume 45, Number 1, January I 1999
|
|
---|---|---|
Page(s) | 65 - 70 | |
Section | Condensed matter: electronic structure, electrical, magnetic and optical properties | |
DOI | https://doi.org/10.1209/epl/i1999-00132-1 | |
Published online | 01 September 2002 |
Atomic origins of the Si 2p surface core-level shifts of the
“prototypical”
-Ag
structure
1
CRMC2-CNRS, Campus de Luminy - Case 913, F-13288 Marseille Cedex 09, France
2
Istituto di Struttura della Materia del CNR, via Fosso del Cavaliere I-00133 Roma, Italy
Received:
30
July
1998
Accepted:
29
October
1998
High-resolution core-level spectra from the -Ag
surface considered as a standard in surface science have been obtained at
100 K. The sharp Si 2p spectra comprise three asymmetric surface-shifted
components, pointing to a metallic character of the surface. The strong S1
component due to the Si first layer atoms bonded to the adsorbed Ag atoms
is shifted
to higher binding energy. This challenges the theoretical
prediction of a large charge transfer from the Ag atoms to this top Si layer
and points to the importance of final-state effects in the interpretation
of the Si 2p spectra.
PACS: 73.20.-r – Surface and interface electron states / 79.60.-i – Photoemission and photoelectron spectra
© EDP Sciences, 1999
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