Issue |
Europhys. Lett.
Volume 50, Number 2, April II 2000
|
|
---|---|---|
Page(s) | 189 - 195 | |
Section | Condensed matter: structure, mechanical and thermal properties | |
DOI | https://doi.org/10.1209/epl/i2000-00253-5 | |
Published online | 01 September 2002 |
Phonon-like and single-particle dynamics in liquid lithium
1
Università di Trento and Istituto Nazionale
di Fisica della Materia I-38100, Trento, Italy
2
Istituto di Elettronica Quantistica,
Consiglio Nazionale delle Ricerche I-50127, Firenze, Italy
3
European Synchrotron Radiation Facility -
B.P. 220 F-38043 Grenoble, Cedex France
4
Università di L'Aquila and Istituto Nazionale
di Fisica della Materia I-67100, L'Aquila, Italy
Received:
22
October
1999
Accepted:
31
January
2000
The dynamic structure factor, S(Q,E), of liquid lithium ()
has been remeasured by inelastic X-ray scattering (IXS) in an extended
momentum transfer region (Q = 1.4–
) and with improved
energy resolution (down to 1.5 meV). These new data on such prototypical
simple liquid allow to observe the full evolution with Q from a phonon-like
collective mode towards the single-particle dynamics. As a function of Q,
one finds: i) at low Q's, a sound mode with a positive dispersion of
the sound velocity, ii) at intermediate Q's, excitations whose energy
oscillates similarly to phonons in the crystal Brillouin zones, and iii)
at high Q's, the S(Q,E) approaches a Gaussian shape, indicating that the
single-particle dynamics has been reached.
PACS: 61.25.Mv – Liquid metals and alloys / 61.10.Eq – X-ray scattering (including small-angle scattering) / 61.20.Ne – Structure of simple liquids
© EDP Sciences, 2000
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