Issue |
Europhys. Lett.
Volume 55, Number 3, August 2001
|
|
---|---|---|
Page(s) | 425 - 431 | |
Section | Interdisciplinary physics and related areas of science and technology | |
DOI | https://doi.org/10.1209/epl/i2001-00431-5 | |
Published online | 01 December 2003 |
Modeling the electrophoretic deposition of colloidal particles
1
Departamento de Electrónica
y Electromagnetismo, Facultad de Física Avda. Reina Mercedes
s/n 41012 Sevilla, Spain
2
Department of Chemical Engineering, Princeton University - Princeton, NJ 08544, USA
Received:
18
December
2000
Accepted:
25
May
2001
This letter presents the results of numerical simulations of the buildup of a layer of colloidal particles on an electrode. In a low-frequency electric field, particles suspended in a low-conductivity liquid migrate to one electrode and then to the other. During each cycle, deposits are formed and dissipated. The current-voltage characteristics of the process reflect properties of the suspension and the deposited layer. Using a flux corrected transport (FCT) algorithm, the transport equation for the particle phase is solved simultaneously with equations describing the electric field. The model reproduces the main features of the current-voltage relation.
PACS: 82.45.-h – Electrochemistry and electrophoresis / 82.70.Dd – Colloids / 47.65.+a – Electrohydrodynamics and magnetohydrodynamics
© EDP Sciences, 2001
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