Issue |
EPL
Volume 81, Number 5, March 2008
|
|
---|---|---|
Article Number | 57004 | |
Number of page(s) | 6 | |
Section | Condensed Matter: Electronic Structure, Electrical, Magnetic and Optical Properties | |
DOI | https://doi.org/10.1209/0295-5075/81/57004 | |
Published online | 04 February 2008 |
Multiferroicity due to nonstoichiometry in the chain cuprate LiVCuO4
1
Ural State University - 620083 Ekaterinburg, Russia
2
Leibniz Institut für Festkörper- und Werkstoffforschung Dresden - D-01171, Dresden, Germany
Received:
6
August
2007
Accepted:
1
January
2008
The recently observed multiferroic behavior in the chain cuprate LiVCuO4 (≡ LiCuVO4) with edge-shared plaquettes and helical spin ordering does not agree with the existing theories such as a spin-current scenario. We argue that the effect can be consistently explained, if the exchange-induced electric polarization on the out-of-chain Cu2+ centers substituting for Li ions in LiVCuO4 is taken into account. These substituent centers are proved to be an effective probe of the spin incommensurability and the magnetic-field effects.
PACS: 74.72.-h – Cuprate superconductors (high-Tc and insulating parent compounds) / 75.10.Pq – Spin chain models / 77.80.-e – Ferroelectricity and antiferroelectricity
© EPLA, 2008
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