Volume 83, Number 4, August 2008
|Number of page(s)||6|
|Section||Atomic, Molecular and Optical Physics|
|Published online||04 August 2008|
Comparative study of the rovibrational properties of heteronuclear alkali dimers in electric fields
Instituto “Carlos I” de Física Teórica y Computacional and Departamento de Física Atómica Molecular y Nuclear, Universidad de Granada - E-18071 Granada, Spain, EU
2 Theoretische Chemie, Physikalisch-Chemisches Institut, Universität Heidelberg - Im Neuenheimer Feld 229, D-69120 Heidelberg, Germany, EU
3 Physikalisches Institut, Universität Heidelberg - Philosophenweg 12, D-69120 Heidelberg, Germany, EU
Corresponding author: firstname.lastname@example.org
Accepted: 25 June 2008
A comparative study of the effect of a static homogeneous electric field on the rovibrational spectra of several polar dimers in their electronic ground state is performed. Focusing upon the rotational ground state within each vibrational band, results for energies and various expectation values are presented. For moderate field strengths the electric-fieldinduced energy shifts, orientation, alignment, and angular-motion hybridization are analyzed up to high vibrational excitations close to the dissociation threshold.
PACS: 33.20.-t – Molecular spectra / 32.60.+i – Zeeman and Stark effects / 33.20.Vq – Vibration-rotation analysis
© EPLA, 2008
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