Volume 85, Number 4, February 2009
|Number of page(s)||5|
|Section||Condensed Matter: Electronic Structure, Electrical, Magnetic and Optical Properties|
|Published online||03 March 2009|
Large magnetic entropy change near room temperature in antiperovskite SnCMn3
Key Laboratory of Materials Physics, Institute of Solid State Physics, and High Magnetic Field Laboratory, Chinese Academy of Sciences - Hefei 230031, PRC
2 Department of Physics, University of Virginia - Charlottesville, VA 22904, USA
Accepted: 28 January 2009
We report the observation of a large magnetocaloric effect near room temperature in the antiperovskite SnCMn3. The maximal magnetic entropy change at the first-order ferrimagnetic-paramagnetic transition temperature ( ~ 279 K) is about 80.69 mJ/cm3 K and 133 mJ/cm3 K under a magnetic field of 20 kOe and of 48 kOe, respectively. These values are close to those of typical magnetocaloric materials. The large magnetocaloric effect is associated with the sharp change of lattice, resistivity and magnetization in the vicinity of . Through the measurements of the Seebeck coefficient and normal Hall effect, the title system is found to undergo a reconstruction of the electronic structure at . Considering its low-cost and innocuous raw materials, Mn-based antiperovskite compounds are suggested to be appropriate for pursuing new materials with larger magnetocaloric effect.
PACS: 75.30.Sg – Magnetocaloric effect, magnetic cooling / 75.50.Gg – Ferrimagnetics / 75.30.Kz – Magnetic phase boundaries (including magnetic transitions, metamagnetism, etc.)
© EPLA, 2009
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