| Issue |
EPL
Volume 88, Number 4, November 2009
|
|
|---|---|---|
| Article Number | 40003 | |
| Number of page(s) | 6 | |
| Section | General | |
| DOI | https://doi.org/10.1209/0295-5075/88/40003 | |
| Published online | 26 November 2009 | |
Superscars in the LiNC 
LiCN isomerization reaction
1
Departamento de Química C-IX, Universidad Autónoma de Madrid - Cantoblanco, 28049 Madrid, Spain, EU
2
Grupo de Sistemas Complejos and Departamento de Física, Escuela Técnica Superior de Ingenieros Agrónomos, Universidad Politécnica de Madrid - 28040 Madrid, Spain, EU
3
Instituto Mixto de Ciencias Matemáticas CSIC-UAM-UC3M-UCM, Universidad Autónoma de Madrid Cantoblanco, 28049 Madrid, Spain, EU
Corresponding author: f.borondo@uam.es
Received:
4
September
2009
Accepted:
27
October
2009
We demonstrate the existence of superscarring in the LiNC LiCN isomerization reaction described by a realistic potential interaction in the range of readily attainable experimental energies. This phenomenon arises as the effect of two periodic orbits appearing “out of the blue” in a saddle-node bifurcation taking place in the dynamics of the system. Potential practical consequences of this superlocalization in the corresponding wave functions are also considered.
PACS: 05.45.Mt – Quantum chaos; semiclassical methods / 03.65.Sq – Semiclassical theories and applications / 82.30.Qt – Isomerization and rearrangement
© EPLA, 2009
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