Signatures of spin-phonon coupling in hematite crystallites through dielectric and Raman spectroscopy

¹ Department of Physics, Indian Institute of Science Education and Research - Dr. Homi Bhabha Road, Pune 411008, India
² Center for Energy Science, Indian Institute of Science Education and Research - Dr. Homi Bhabha Road, Pune 411008, India

^(a) ashna@iiserpune.ac.in (corresponding author)

Received: 2 March 2021
Accepted: 2 June 2021

Abstract

We report complex dielectric and Raman spectroscopy measurements in hematite crystallites, which are either hexagon-shaped plates or cuboids. Temperature variation of magnetization data in all these samples exhibits sharp Morin transition (T_M). Moderate but clear enhancement in the real part of the dielectric constant is observed in the vicinity of the T_M in all the samples. However a relaxation-like behavior in the imaginary part is observed only in nanoplates or big cuboids across the T_M. The real part of the dielectric constant fits well to the modified-Barrett equation above T_M (in the spin-canted region), whereas clear deviations are observed below T_M (in the pure antiferromagnetic region). The frequency of the phonon mode, deduced from the Barrett fitting, matches with the E_u Raman mode of hematite. Temperature-dependent Raman spectra reveal anomalies in all major phononic modes in the vicinity of the T_M. Anharmonic fitting of the temperature-dependent Raman and modified-Barrett fitting of the dielectric data brings forward modifications in spin-phonon coupling in the vicinity of the Morin transition temperature in hematite.