Issue |
Europhys. Lett.
Volume 58, Number 2, April 2002
|
|
---|---|---|
Page(s) | 299 - 305 | |
Section | Interdisciplinary physics and related areas of science and technology | |
DOI | https://doi.org/10.1209/epl/i2002-00637-5 | |
Published online | 01 August 2002 |
Morphologies of semiflexible polyelectrolyte complexes
1
Max-Planck-Institut für Kolloid-
und Grenzflächenforschung 14424 Potsdam, Germany
2
Sektion Physik, LMU - Theresienstr. 37, 80333 München, Germany
Received:
9
October
2001
Accepted:
28
January
2002
Complexation between a stiff charged cylinder and an oppositely charged semiflexible polymer is studied using linear Debye-Hückel theory (valid for large enough salt concentration or weakly charged polymers). The salt-concentration–dependent phase diagram features helical and, favored for increasing stiffness of the wrapping polymer, straight wrapping morphologies. Non-linear (counterion release) effects are discussed on the scaling level.
PACS: 82.70.-y – Disperse systems; complex fluids / 87.15.-v – Biomolecules: structure and physical properties / 82.45.-h – Electrochemistry and electrophoresis
© EDP Sciences, 2002
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