Volume 40, Number 6, December II 1997
|Page(s)||655 - 660|
|Section||Condensed matter: structure, thermal and mechanical properties|
|Published online||01 September 2002|
Observation of nano-dewetting structures
Max-Planck-Institut für Polymerforschung -
Ackermannweg 10, 55128 Mainz, Germany
Accepted: 6 November 1997
We have studied the dewetting of thin polymer films (polystyrene) on top of different silicon substrates. With diffuse X-ray scattering and scanning-force microscopy a high in-plane resolution was achieved. Besides the well-known mesoscopic dewetting structures of drops with diameters in the range of several micrometers we detect a further morphological feature. Depending on the thickness of the native silicon oxide layer, inside the dewetted areas small dimples are formed. This nano-dewetting structure can be understood as the result of the dewetting of a remaining ultra-thin film and is compared with theoretical predictions of spinodal decomposition. This observation of another length scale provides some new aspects on the molecular mechanism of polymer dewetting.
PACS: 68.45.Gd – Wetting / 68.55.Jk – Structure and morphology; thickness / 83.10.Nn – Polymer dynamics
© EDP Sciences, 1997
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