Issue |
Europhys. Lett.
Volume 73, Number 3, February 2006
|
|
---|---|---|
Page(s) | 390 - 395 | |
Section | Condensed matter: structural, mechanical and thermal properties | |
DOI | https://doi.org/10.1209/epl/i2005-10416-4 | |
Published online | 04 January 2006 |
Boundary flow of water on supported phospholipid films
Laboratoire de Physique de la Matière Condensée et Nanostructures Université Claude Bernard Lyon 1 et CNRS, UMR 5586 - F-69622 Villeurbanne, France
Received:
20
September
2005
Accepted:
9
December
2005
We report an investigation of the boundary flow of water on DPPC
monolayers and bilayers deposited on Pyrex surfaces, using a
dynamic surface force apparatus. We find that a no-slip boundary
condition is verified at the water/bilayer interface within .
In contrast, the interfacial flow properties on monolayers evolve
with the time of exposure to water. A significant slip of
is
found on fresh monolayers, which are strongly hydrophobic. The
hydrodynamic interaction force with a nearby surface is then
significantly reduced over hundreds of nanometers. This slip
effect disappears after one day of exposure to water, due to the
increased hydrophilicity and roughness of hydrated monolayers.
PACS: 68.08.-p – Liquid-solid interfaces / 68.47.Pe – Langmuir-Blodgett films on solids; polymers on surfaces; biological molecules on surfaces / 83.50.Rp – Wall slip and apparent slip
© EDP Sciences, 2006
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