Issue |
EPL
Volume 85, Number 3, February 2009
|
|
---|---|---|
Article Number | 36003 | |
Number of page(s) | 6 | |
Section | Condensed Matter: Structural, Mechanical and Thermal Properties | |
DOI | https://doi.org/10.1209/0295-5075/85/36003 | |
Published online | 13 February 2009 |
Depletion interaction of two spheres —Full density functional theory vs. morphometric results
1
Institut für Physik, WA 331, Johannes-Gutenberg-Universität Mainz - D-55099 Mainz, Germany, EU
2
Max-Planck-Institut für Metallforschung - Heisenbergstr. 3, 70569 Stuttgart, Germany, EU
3
ITAP, Universität Stuttgart - Pfaffenwaldring 57, 70569 Stuttgart, Germany, EU
4
Department for the Modeling of Physico-Chemical Processes, Maria Curie-Sklodowska University 20-031 Lublin, Poland, EU
Corresponding author: oettelm@uni-mainz.de
Received:
19
December
2008
Accepted:
19
January
2009
Morphological thermodynamics is employed to calculate the depletion potential between two big hard spheres in a solvent of small spheres. Thereby, the potential is characterized solely by the geometric properties of the solvent-accessible surface of the two-sphere configuration in the depletion region. Comparison with explicit density functional theory calculations using accurate functionals of the fundamental measure type shows good agreement.
PACS: 61.20.-p – Structure of liquids / 82.70.Dd – Colloids
© EPLA, 2009
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