Volume 106, Number 4, May 2014
|Number of page(s)||6|
|Section||Condensed Matter: Structural, Mechanical and Thermal Properties|
|Published online||29 May 2014|
Improved leakage current density in Fe3+/Fe2+-doped epitaxially grown Ba0.6Sr0.4TiO3 thin films based on the domain matching model
State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences - 1295 Ding Xi Road, Shanghai, 200050, PRC
Received: 9 February 2014
Accepted: 8 May 2014
A doping mode and its mechanism are proposed for Fe3+/Fe2+-doped (Ba,Sr)TiO3 thin films of the perovskite structure (ABO3), in which the substitutions of Fe3+/Fe2+ for the B site are coexisting to match the lattice distortion and release the strain energy, which is kind of like “domain matching”. Experimental results indicated that Fe dopant had little effect on the epitaxial growth of Ba0.6Sr0.4TiO3 thin films, but had much effect on the suppression of defects such as oxygen vacancies, and the reduction of the leakage current density. With different Fe dopants, the Poole-Frenkel emission, the Schottky junction and the ohmic-like contact separately dominated the leakage current in different voltage regions.
PACS: 68.65.Ac – Multilayers / 61.72.U- – Doping and impurity implantation / 73.40.Sx – Metal-semiconductor-metal structures
© EPLA, 2014
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.